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When they are kept together in their protective wrap, the arrows can be used as a ward of sorts to defend against magic spells.
Hiroko Takashiro uses the arrows in defense against the evil witch Jody Crowley and her two guards. She later magically shoots four arrows at Crowley to stop her from completing the Ritual of Coronzon in the Academy basement. She throws the final arrow at the Bible Black spell book when it resurfaces in an attempt to break its seal.